Copper-catalyzed oxidative synthesis of 2-oxo-acetamidines from one-pot three-component reaction of aryl methyl ketones, secondary amines and anilines

Add time:07/12/2019    Source:sciencedirect.com

Some novel 2-oxo-acetamidines were synthesized via one-pot three-component reaction of acetophenones, secondary amines and anilines in presence of CuI as catalyst. The reaction involved in a oxidation process of C (sp3)H bonds of acetophenones in presence of air followed by aminations, and products were obtained in good to excellent yields (70–82%) in simple work-up procedure.

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