Sulfur-directed metal-free and regiospecific methyl C(sp3)–H imidation of Thioanisole (cas 100-68-5)s

Add time:07/20/2019    Source:sciencedirect.com

Regiospecific and direct imidation of the methyl C(sp3)–H bond of thioanisoles is realized under mild and metal-free conditions with N-fluorobis(benzenesulfonyl)imide as an oxidant and nitrogen source. Proposed mechanism suggests that thionium ion intermediates and a Pummerer-type reaction are involved. The imidation has advantages such as high step-economy, excellent functionality tolerance, and regiospecificity, giving structurally diverse imidation products.

We also recommend Trading Suppliers and Manufacturers of Thioanisole (cas 100-68-5). Pls Click Website Link as below: cas 100-68-5 suppliers

Prev:Thioanisole (cas 100-68-5) triplet: Laser flash photolysis and pulse radiolysis studies
Next:Metal-size influence in isoselective 2-Vinylpyridine (cas 100-69-6) polymerization)