Mechanistic studies on the reduction of 2-bromo-1-phenylethylidenemalononitrile by NADH models BNAH and AcrH2

Add time:07/19/2019    Source:sciencedirect.com

Reduction of 2-bromo-1-phenylethylidenemalononitrile (BPM) by coenzyme NADH models BNAH and AcrH2 to give 2-phenyl-1, 1-cyclopropanedicarbonitrile (PCN) and 1-phenylethylidenemalononitrile (PM), respectively, was rationalized in terms of a direct hydride transfer with BNAH and an initial electron transfer with AcrH2.

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