Cyclometallated compounds
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Add time:07/21/2019 Source:sciencedirect.com
The dioximes of 1,3- and 1,4-diacetylbenzene readily undergo regioselective double cyclopalladation on reaction with lithium tetrachloropalladate. 1,5-Bis(dimethylamino)naphthalene has been singly and doubly cyclopalladated; attempts to prepare heterodicyclometallated derivatives of this ligand were not successful. An X-ray crystal structure of the singly cyclometallated Pd(acac) complex of 1,5-bis(dimethylamino)naphthalene has been determined.
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Next:Structural and thermal studies of non-metal cation pentaborate salts with cations derived from 1,5-diazobicyclo[4.3.0]non-5-ene, 1,8-diazobicyclo[5.4.0]undec-7-ene and 1,8-bis(dimethylamino)naphthalene) - 【Back】【Close 】【Print】【Add to favorite 】
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