A convenient stereoselective synthesis of conjugated (2Z)-EN-4-ynoic and (2Z,4Z)- and (2Z,4E)-dienoic acid derivatives from propiolic acid derivatives
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Add time:07/14/2019 Source:sciencedirect.com
The palladium-catalyzed one-pot sequential reaction of propiolic acid derivatives with lithium halides first, and then with terminal alkynes or alkenes affords conjugated (2Z) -en-4-ynoic and (2Z,4Z)- and (2Z,4E)- dienoic acid derivatives with high stereoselectivity.
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