Pernitrated metalloporphyrins as catalysts in oxidation with magnesium monoperoxophthalate

Add time:07/19/2019    Source:sciencedirect.com

The system composed of manganese (2,6)-dichlorotetraphenyl- or pentafluorotetraphenyl-porphyrins, bearing nitro groups at the β-pyrrolic positions as catalysts and monoperoxyphthalic acid magnesium salt (MMPP) as oxidant is an efficient model system for epoxidation of dodecene-1 and propene. A comparison with the corresponding system based on iron and cobalt complexes as well as the influence of the addition of a nitrogenous base are also described.

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