A novel cyclization reaction of oxido diazoalkanes: formation of 1-substituted cycloalkenes

Add time:07/21/2019    Source:sciencedirect.com

The thermal decomposition of dialkali metal salts of δ-hydroxybutyl ketone and ε-hydroxypentyl ketone tosylhydrazones in diglyme at 80–120 °C produced the 1-substituted cyclopentene and cyclohexene, respectively.

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