Subvalent bismuth monocation Bi+ photoluminescence in ternary halide crystals KAlCl4 and KMgCl3
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Add time:07/13/2019 Source:sciencedirect.com
Monocation Bi+ isomorphically substitutes potassium in KAlCl4 and KMgCl3 chlorides. Having the unique 6p2 open-shell electronic configuration, Bi+ possesses a number of low-lying excited states, and displays broadband long-lived NIR photoluminescence in ternary chloride crystals.
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