KMnO4-mediated oxidative CN bond cleavage of tertiary amines: Synthesis of amides and sulfonamides
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Add time:07/23/2019 Source:sciencedirect.com
KMnO4-mediated oxidative CN bond cleavage of tertiary amines producing secondary amine was introduced, which was trapped by electrophiles (acyl chloride and sulfonyl chloride) to form amides and sulfonamides. The reaction could take place at mild condition, tolerating a wide range of function groups and affording products in moderate to excellent yields.
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