The N-alkylation of 4-nitrobenzochalcogenadiazoles: Synthesis and theoretical approach
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Add time:07/21/2019 Source:sciencedirect.com
A facile synthetic method for N-alkylated substituted benzochalcogenadiazoles is described. When treated with Meerwein salt, the 4-nitrobenzochalcogenadiazoles have undergone an N-alkylation to afford the expected salts as a mixture of two N1/N3 isomers in toluene. The regioselectivity of the alkylation reaction was then confirmed by spectroscopic data as well as theoretical calculations.
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