Synthesis, characterization and investigation of electrochemical and spectroelectrochemical properties of peripherally tetra 4-phenylthiazole-2-thiol substituted metal-free, zinc(II), copper(II) and cobalt(II) phthalocyanines

Add time:07/23/2019    Source:sciencedirect.com

In this study novel peripherally tetra 4-phenylthiazole-2-thiol substituted metal-free phthalocyanine (4) and its zinc(II) (5), copper(II) (6) and cobalt(II) (7) derivatives were synthesized and characterized by a combination of various spectroscopic techniques such as FT-IR, 1H-NMR, UV–vis and MALDI-TOF mass. Electrochemical characterizations of metallo-phthalocyanine complexes were conducted by voltammetric and in situ spectroelectrochemical measurements. CoIIPc went [CoIIPc−2]/[CoIPc−2]1-, [CoIPc−2]1-/[CoIPc−3]2-, [CoIPc−3]2-/[CoIPc−4]3- and [CoIIPc−2]/[CoIIPc−2]1+ reduction and oxidation processes respectively. Differently ZnIIPc only showed four ligand-based reductions and two ligand based oxidation processes.

We also recommend Trading Suppliers and Manufacturers of COPPER(II) PHTHALOCYANINE-3 4' 4'' 4'''& (cas 123439-80-5). Pls Click Website Link as below: cas 123439-80-5 suppliers

Prev:Synthesis, characterization and comparative electrochemistry of beta and alpha tetra-[4-oxy-3-methoxybenzoic acid]-substituted Zn(II), Co(II) and Cu(II) phthalocyanines
Next:Synthesis, characterization and investigation of cholinesterase inhibitory properties of novel peripherally tetra substituted metal-free and metallo-phthalocyanines)