Acyl C→N migration in the thioureidomethylation of 2-(4-methylbenzoyl)cyclohexanone
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Add time:07/21/2019 Source:sciencedirect.com
The thioureidomethylation of the sodium enolate of 2-(4-methylbenzoyl)cyclohexanone 3 with N-(tosylmethyl)thiourea 1a or N-(azidomethyl)thiourea 2 in acetonitrile results in the unexpected formation of N-(4-methylbenzoyl)-N’-[(2-oxocyclohexyl)-methyl]thiourea 6, which was structurally characterised by X-ray diffraction analysis.
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