Trialkyl borate assisted amination of fluorinated 1,3-diketones for synthesis of N,N′-1,2-phenylen-bis(β-aminoenones) and their Ni(II), Cu(II) and Pd(II) complexes

Add time:07/20/2019    Source:sciencedirect.com

An effecient synthetic method for fluorinated tridentate β-aminoenones and tetradentate bis(β-aminoenones) via amination of fluorinated 1,3-diketones with o-phenylenediamine in the presence of trialkyl borates was developed. Ni(II), Cu(II) and Pd(II) complexes with tetradentate bis(β-aminoenones) were obtained. Their gaschromatographic behaviour and main fragmentation paths in the electron ionization mass spectra were described.

We also recommend Trading Suppliers and Manufacturers of N,N'-Bis(2'-aminophenyl)ethylene diamine (cas 16825-43-7). Pls Click Website Link as below: cas 16825-43-7 suppliers

Prev:Augmentation of GABAergic neurotransmission by novel N-(substituted)-2-[4-(substituted)benzylidene]hydrazinecarbothioamides—A potential anticonvulsant approach
Next:Ammonium–cobalt–nickel phosphates, NH4[Co1−xNixPO4]·H2O)