Transformation of 1-(1,2-propadienyl)cyclopropanols into substituted hydroquinones employing octacarbonyldicobalt

Add time:07/22/2019    Source:sciencedirect.com

A novel transformation of 1-(1,2-propadienyl)cyclopropanols into substituted 1,4-hydroquinones has been developed utilizing the interaction of 1,2-propadienes and octacarbonyldicobalt (Co2(CO)8). This reaction was applied to the synthesis of vitamin E and K analogs.

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