Intermediate oxidation states of Technetium (cas 109581-73-9) in concentrated sulfuric acid solutions

Add time:07/30/2019    Source:sciencedirect.com

The electrochemical reduction of pertechnetate ions (TcO4−) and properties of such formed reduced Tc containing species (ions and molecules) have been studied in strongly acidic media (4 ÷ 12 M aqueous H2SO4) using electrochemical (cyclic voltammetry (CV); chronoamperometry (CA), chronopotentiometry (CP)) and spectroelectrochemical (UV-VIS OTTLE and Au-SERS) techniques. The results show generation of Tc(V) containing species in the first steps of the pertechnetate electroreduction. The experiments carried out in 6, 8 and 10 M H2SO4 have shown that an increase in the acid concentration shifts the Tc(VII) electroreduction wave towards positive potential values. Additional Au-SERS experiments indicate generation of Tc species with intermediate oxidation states (V) characterised by a band at 792 cm−1 that are distinguishable from TcO2 or polymeric Tc(IV) forms. Application of derivative pulse techniques allows determination of pertechnetates in strongly acidic solutions at a level of 10−6 mol/dm3 even in the presence of impurities, such as Fe3+ and Cl-, with concentrations comparable or greater than pertechnetates.

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