Solvent-free multicomponent reactions using the novel N-sulfonic acid modified poly(styrene-maleic anhydride) as a solid acid catalyst

Add time:07/24/2019    Source:sciencedirect.com

A new N-sulfonic acid based on the polymer-support as a solid acid catalyst is prepared by the reaction of the modified poly(styrene-alt-maleic anhydride) with neat chlorosulfonic acid. 4H-Pyrimido[2,1-b]benzothiazole derivatives, tetrasubstituted imidazoles and benzoxanthenones as selected solvent-free multicomponent reactions were successfully synthesized using this catalyst. These eco-friendly protocols offer several advantages such as green and cost-effective procedures with excellent yield, shorter reaction time, simpler work-up, recovery, and reusability of metal-free solid acid heterogeneous catalyst along with tolerance of a wide range of functional groups.

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