Stereochemical proof for front side deuteride attack via σ-sulfurane in the reductive desulfinylation of sulfoxides with lithium aluminum deuteride

Add time:07/27/2019    Source:sciencedirect.com

Stereochemical results obtained from the concomitant reduction and desulfinylation of 1-phenyl-2-pyridyl-2(p-tolysulfinyl)- and 1,2-diphenyl-2-phenylsulfinyl ethanols with lithium aluminum deuteride reveal that the reactions proceed stereospecifically via σ-sulfurane as a common intermediate.

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