Enantioselective synthesis of γ-lactones from thioglycolic acid: Syntheses of (−)-muricatacin and 5-epi-(−)-muricatacin1

Add time:07/23/2019    Source:sciencedirect.com

An approach for the enantioselective synthesis of functionalized γ-lactones and its application to the syntheses of (−)-muricatacin 1a and 5-epi-(−)-muricatacin 1b is reported. A sequential oxidation of the intermediate 4 with m-chloroperoxybenzoic acid was conducted to realize the reaction mechanism.

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