Vibrational spectra and structures of zinc carboxylates II. Anhydrous zinc acetate and zinc stearate
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Add time:07/26/2019 Source:sciencedirect.com
A normal mode analysis was carried out for a monoclinic anhydrous zinc acetate crystal in which the acetate groups had bridging bidentate coordination forms, and spectral assignments were made. Based on the assignments, a relation between the coordination structure of the carboxylate groups around the zinc atom and the vibrational frequencies of the carboxylate rocking mode was found. This relation was applied to zinc stearate to determine its coordination form, and we found that zinc stearate had a bridging bidentate form.
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