Cadmium(II) complexes with [(4-methylphenyl)sulfonyl]-2-pyridyl-amine: crystal structures of bis{[(4-methylphenyl)sulfonyl]-2-pyridyl-amide}cadmium(II); aquo-bis(pyridine) bis{[(4-methylphenyl)sulfonyl]-2-pyridyl-amide}cadmium(II) and 1,10-phenanthroline bis{[(4-methylphenyl)sulfonyl]-2-pyridyl-amide}cadmium(II)

Add time:07/12/2019    Source:sciencedirect.com

Electrochemical oxidation of cadmium in a solution of [(4-methylphenyl)sulfonyl]-2-pyridyl-amine (HL) in acetonitrile/dichloromethane afforded the compound [CdL2]. When pyridine (py), 2,2′-bipyridine (bipy) or 1,10-phenanthroline (phen) was added to the electrolytic phase, [CdL2py2(H2O)], [CdL2bipy] and [CdL2phen] were obtained. The crystal structures of [CdL2] (1), [CdL2py2(H2O)] (2) and [CdL2phen] (3) have been determined by X-ray diffraction techniques. The complex [CdL2] is best described in terms of a linear polymer with the metal atom in a [CdN4O2] distorted octahedral environment. The [CdL2py2(H2O)] and [CdL2phen] complexes are monomeric, with the cadmium atoms in [CdN6O] distorted pentagonal bipyramid and [CdN6] trigonal prismatic environments, respectively.

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