Electroinduced Carbene Formation in the Cathodic Reduction of 1,2-Dicarbonyl Compounds via Electron-Transfer to the Solvent
-
Add time:07/23/2019 Source:sciencedirect.com
Electrochemical reduction of 9,10-phenanthrenequinone, benzil and acenaphthenequinone in 1,1,1-trichloroethane (TCE)/TBAP under constant potential conditions provides an interesting entry to new coupling products through an electron-transfer reaction in solution to the chlorinated solvent. This electroinduced reaction points out the differences in the reaction pathway followed by these 1,2-dicarbonyl compounds depending on their geometry. The intermediates nature and their behavior, both in solution and at the electrode surface, are discussed.
We also recommend Trading Suppliers and Manufacturers of 2-(1,2-Dichloroethyl)-4-methyl-1,3-dioxolane (cas 10232-90-3). Pls Click Website Link as below: cas 10232-90-3 suppliers
Prev:A colourful azulene-based protecting group for carboxylic acids
Next:Ab initio CI study of the laser radiation effect on pyrolysis of 1,2-dichloroethane) - 【Back】【Close 】【Print】【Add to favorite 】
- Related Information
- Sulfur-containing proreactive intermediates: hydrolysis and mutagenicity of halovinyl 2-nitrophenyl disulfides07/27/2019
- Brain-acetylcholinesterase inhibition in a marine teleost during lethal and sublethal exposures to 1,2-dibromo-2,2-dichloroethyl dimethyl phosphate (naled) in seawater07/26/2019
- Activity of organophosphorus insecticides in bacterial tests for mutagenicity and DNA repair — Direct alkylation versus metabolic activation and breakdown. II. O,O-dimethyl-O-(1,2-dibromo-2,2-dichloroethyl)-phosphate and two O-ether derivatives of trichlorfon07/25/2019
- Ab initio CI study of the laser radiation effect on pyrolysis of 1,2-dichloroethane07/24/2019
