Papain-catalyzed aldol reaction for the synthesis of trifluoromethyl carbinol derivatives
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Add time:07/11/2019 Source:sciencedirect.com
Papain from Carica papaya demonstrated catalytic promiscuity was first discovered to catalyze the synthesis of trifluoromethyl carbinol derivatives via aldol reaction between α,α,α-trifluoromethyl ketones and aliphatic ketones in a mixed solvent of DMF and water. The best results of the corresponding aldol products with up to 99% yield and 30% ee were achieved.
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