Thermochemical studies of 4-tert-butylbiphenyl and 4,4′-di-tert-butylbiphenyl

Add time:07/24/2019    Source:sciencedirect.com

The standard massic energies of compounds of 4-tert-butylbiphenyl and 4,4′-di-tert-butylbiphenyl were measured at T = 298.15 K by static-bomb combustion calorimetry. The standard enthalpies of vaporization, fusion and sublimation were measured in a Calvet microcalorimeter, or by differential scanning calorimetry. The standard molar enthalpies of formation in the condensed and gaseous states were obtained from these data. The tert-butyl group increments for the substitution of one hydrogen atom in a position “4” in biphenyl molecule were calculated.

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