Free-radical oxidation of para-substituted phenols by hypervalent tert-butylperoxyiodane and tert-butyl hydroperoxide: Synthesis of 4-(tert-butylperoxy)-2,5-cyclohexadien-1-ones

Add time:07/26/2019    Source:sciencedirect.com

Oxidation of 4-alkylphenols 1 by 1-(tert-butylperoxy)-1,2-benziodoxol-3(1H)-one (2) in the presence of tert-butyl hydroperoxide affords selectively 4-(tert-butylperoxy)-2,5-cyclohexadien-1-ones 3 in good yields. Evidence for the involvement of free-radicals is reported.

We also recommend Trading Suppliers and Manufacturers of 2,5-Di(tert-butylperoxy)-2,5-dimethyl-3-hexyne (cas 1068-27-5). Pls Click Website Link as below: cas 1068-27-5 suppliers

Prev:A green approach towards adoption of chemical reaction model on 2,5-dimethyl-2,5-di-(tert-butylperoxy)hexane decomposition by differential isoconversional kinetic analysis
Next:The chemistry of aminoguanidine derivatives – preparation, crystal structure, thermal properties, and molecular docking studies of aminoguanidinium salts of several carboxylic acids)