Divinyl sulfides/sulfones-based D–π–A–π–D dyes as efficient non-aromatic bridges for π-conjugated compounds

Add time:07/24/2019    Source:sciencedirect.com

Novel photoactive divinyl sulfides and sulfones have been obtained by a straightforward approach using a Wittig–Horner reaction. These compounds behave as quadrupolar chromophores and show absorption in the UV region and fluorescence emission tailored by the solvent polarity due to an intramolecular charge transfer mechanism in the excited state, confirmed by the large Stokes' shift and the positive solvatochromism exhibited by their fluorescence spectra. In particular, a large Stokes' shift has been achieved for the sulfone containing the carbazole moiety, which behaves like a “push–pull” architecture. These new molecules represent an efficient alternative as stable non-heterocyclic π-conjugated compounds for potential applications as photoactive or two-photon absorption chromophores.

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