The radical homopolymerization of N-phenylmaleimide, N-n-hexylmaleimide and N-Cyclohexylmaleimide (cas 1631-25-0) in tetrahydrofuran

Add time:07/25/2019    Source:sciencedirect.com

The kinetics and mechanisms of thermally initiated (using 2,2′-azobisisoburyronitrile (AIBN) as initiator) radical homopolymerizations of a series of maleimides, including N-phenymaleimide (PHMI) [1-phenyl-1H-pyrrole-2,5-dione]; N-n-hexylmaleimide (nHMI) [1-(n-hexyl)-1H-pyrrole-2,5-dione]; and N-cyclohexylmaleimide (CHMI) [1-cyclohexyl-1H-pyrrole-2,5-dione] have been investigated in THF solution by an on-line FT-NIR technique. It was found that the order of the activation energies for the three N-sub-MIs is: EaPHMI

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