Salts with the [NiBr3(L)]− complex anion (L = 1-methylimidazole, 1-METHYLBENZIMIDAZOLE (cas 1632-83-3), quinoline, and triphenylphosphane) and low melting points: A comparative study

Add time:07/31/2019    Source:sciencedirect.com

Four new salts with low melting points of the general formula (EMIm)[NiBr3(L)] (EMIm = 1-ethyl-3-methyl-imidazolium) with L = N-methylimidazole (NMIm), N-methylbenzimidazole (NMBIm), quinoline (quin), and triphenylphosphane (PPh3) were prepared and characterized by means of elemental analysis, IR, NMR, and UV–vis spectroscopy. Magnetic properties were deduced from NMR data using the EVANS method. All four compounds are paramagnetic with magnetic moments close to the spin-only values of the tetrahedrally coordinated Ni(II) ion. Molecular and crystal structures were obtained by single crystal X-ray diffraction investigations. Melting points are determined to have values between 110 °C, (EMIm)[NiBr3(NMIm)] and 168 °C, (EMIm)[NiBr3(PPh3)]. They exceed the maximum temperature required to call them “Ionic Liquids”. Decomposition has been found to occur above 200 °C and to depend largely on the type of organic ligand coordinated to Ni(II).

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