The synthesis of allylic phosphate derivatives of trans zeatin
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Add time:07/28/2019 Source:sciencedirect.com
Phosphitylation of the allylic hydroxy group in 9-tetrahydropyranyltrans-zeatine with salicyl chlorophosphite gives the allyl phosphonate monoester 5, which can be readily converted into the corresponding phosphate 7, methylphosphate 8 or thiophosphate 9. After cleavage of the tetrahydropyranyl group under mild acidic condition allylic phosphate derivatives of trans-zeatin are obtained.
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