The hydrothermal decomposition of ALUMINUM FLUORIDE TRIHYDRATE (cas 15098-87-0). Kinetics and mechanism

Add time:07/27/2019    Source:sciencedirect.com

The hydrothermal decomposition of AlF3.3H2O in water suspension was investigated by chemical and X-ray analyses at temperatures ranging from 114 to ca. 143°C. It was found that this process runs from a trihydrate to a monohydrate composition according to a zero order rate equation to give subsequently Al(OH,F)3.H2O and β -AlF3.H2O direct from solution and α -AlF3.H2O by conversion of solid trihydrate. Reactions involved in the process are discussed in detail.

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