Lamellar structures in NEODYMIUM BORIDE (cas 12008-23-0)s

Add time:07/24/2019    Source:sciencedirect.com

Samples with the nominal composition Nd2B5 contain strongly disordered crystals composed of nanosized (100) lamellae. Most commonly, a polysynthetic twinning based on a fourfold rotation separates the lamellae at coherent boundaries. The structure of the twin interface contains a pseudo fourfold arrangement of B atoms as derived from electron microscopy techniques. Such pseudo-symmetry serves for a rationalization of the twinning. Additionally, a chemical intergrowth of Nd2B5 and NdB4 lamellae based on related structural building units can be observed. Further HRTEM examinations allow the identification of a new structural variant of neodymium borides.

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