On the californium oxide system

Add time:07/24/2019    Source:sciencedirect.com

Californium dioxide was prepared by oxidation with high pressure molecular oxygen and by atomic oxygen. The CfO2 has a fcc structure with an expansion corrected lattice parameter of 5·310 ± 0·002 Å. Several areas of oxide stability in the range CfOχ(2·00 > χ > 1·50) are reported and these phases have a rhombohedral structure. The phase transition temperature between the body-centered cubic Cf2O3 and monoclinic Cf2O3 is ∼ 1400°C.

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