Meta/para-selectivity variation by sulfide/sulfoxide conversion of 6-substituted β-cyclodextrin. Hydrolyses of nitrophenyl acetates. ag

Add time:07/25/2019    Source:sciencedirect.com

Hydrolyses of m- and p-nitrophenyl acetates by 6-deoxy-6-alkylthio-β-cyclodextrins and the corresponding sulfoxides were studied to show that the small chemical conversion from the sulfides to the sulfoxides led to a change of meta/para-selectivity in the hydrolysis of the β-cyclodextrin moiety.

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