Preparation and polymerization of 1,4-cyclooctadiene
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Add time:07/26/2019 Source:sciencedirect.com
1,4-Cydooctadiene can isolated by careful rectification of reaction mixtures resulting from the isomerization of 1,5-cyclooctadiene with the catalyst system Ti(OBu)4/AlEt3. Its polymerization with metathesis catalysts yields a polybutadiene-like rubber with the structure of an alternating copoly-(propen-penten) amer. Low molecular weight types are oxidatively drying oils which, after further isomerization, contain up to 44% conjugated double bonds and exceed Chinese wood oil (tung oil) in drying rate.
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