Quantitative treatment of rate enhancement due to f-strain in the solvolysis of Z-2-ethylidene-1-adamantyl mesylate and halides

Add time:07/25/2019    Source:sciencedirect.com

The Z:E ratios for the trifluoroethanolysis at 25°C of the title mesylate, chloride, bromide, and iodide are 126, 1020, 2230, and 9680, respectively, whose logarithms are linearly correlated with MM2 steric energies and Hansch's Es values.

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