Synthesis and structure of Nb3SiTe6, a new layered ternary NIOBIUM TELLURIDE (cas 12034-83-2) compound

Add time:07/29/2019    Source:sciencedirect.com

Nb3SiTe6, a new type of layered ternary telluride compound, has been synthesized. The structure is determined by single-crystal X-ray diffraction methods. The compound crystallizes in space group Pnma (No. 62) with Z=4, a=6.353(2) Å, b=13.938(5) Å, c=11.507(4) Å, V=1018.9(6) Å3, R=4.77% and Rw=4.88%. The structure contains sheets of mixed niobium and silicon with tellurium atoms capping both sides. The layered framework has an unusual coordination environment.

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