Structural studies of diorganotin(IV) bischelates. Crystallographic evidence of seven-coordinate tin in bis(2-carbomethoxyethyl)bis (N,N-dimethyldithiocarbamato)tin(IV), [MeOC(O)(CH2)2]2Sn[SC(S)NMe2]2

Add time:07/26/2019    Source:sciencedirect.com

The crystal structure of bis(2-carbomethoxyethyl)bis(N,N-dimethyldithiocarbamato)tin(IV) was determined from 2495 observed Mo-Kα reflections and refined to an R factor of 0.053 (space group P21/c; a 15.629(4), b 10.574(3), c 16.118(4) Å; β 117.00(2)°; V 2373(1) Å3; Z = 4). The compound is monomeric and the tin is seven-coordinate in a distorted pentagonal bipyramid with the organic groups in apical positions (CSnC 154.3(3)°; the pentagonal girdle is made up of the four sulfur atoms of the anisobidentate dithiocarbamato ligands and the carbonyl oxygen atom of a bent apical organic group (SnS (short) 2.571(2), 2.598(2); SnS (long) 2.848(2), 2.913(2); SnO 2.751(5) Å). The oxygen atom and one sulfur atom are displaced equally but oppositely by 0.24(3) Å from the pentagonal least-squares plane, and the tin atom by 0.054(1) Å. The compound is six-coordinate in CDCl3 solution, as shown by ambient 13C NMR data; the one-bond coupling constant, 1J(119Sn13C), has the value 794.2 Hz, consistent with the lower coordination state. There is some evidence, however, of retention of the seven-fold coordination in pyridine solution.

We also recommend Trading Suppliers and Manufacturers of (S)-(-)-2-(2'-CARBOMETHOXYETHYL)-2-METHYLCYCLOHEXANONE (cas 112898-44-9). Pls Click Website Link as below: cas 112898-44-9 suppliers

Prev:Increased affinity and selectivity of enkephalin tripeptide (Tyr-D-Ala-Gly) dimers
Next:Six-coordinate tin in a dialkylchlorooxinatotin(IV) complex: skew-trapezoidal bipyramidal bis(2-carbomethoxyethyl)chloro(quinolin-8-olato)tin(IV))