Methyl group replacement on pentamethylantimony (cas 15120-50-0) with organophosphorus substituents

Add time:07/26/2019    Source:sciencedirect.com

Phosphinic and phosphonic acids were treated with pentamethylantimony (cas 15120-50-0) to replace one of its methyl groups (with formation of methane) to give the following new compounds: (CH3SbOP(O)(C6H5)2, (CH3)4SbOP(O)(OH)CH3, and (CH3)4SbOP(O)(OH)C6H5). The latter two compounds are associated, presumably through hydrogen bonding.

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