The oxidative addition of benzyl halides to tetrakis(triphenylphosphine)nickel(O)
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Add time:07/27/2019 Source:sciencedirect.com
The oxidative addition of benzyl chloride or bromide to tetrakis(triphenylphosphine)nickel(O) followed by carbonylation and the addition of methanol yielded methyl phenylacetate. When (R)-α-D benzyl chloride was subjected to this reaction sequence, racemic ester was obtained, probably as a result of racemization in the oxidative, addition step.
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