Solid-state molybdenum sulfide clusters with an octahedral metal framework as hydrogenation, dehydrogenation, and hydrogenolysis catalysts similar to the platinum group metals

Add time:07/30/2019    Source:sciencedirect.com

Solid-state molybdenum sulfide clusters with a nonstoichiometric sulfur-deficient site, CuxMo6S8−δ (x = 2.94 and δ ≈ 0.3) and Mo6S8–δ (δ ≈ 0.4), catalyze the dehydrogenation of cyclohexene, the hydrogenation of alkyne, alkene, aldehyde, ketone, and nitrobenzene, and the hydrogenolysis of halogenobenzenes in a hydrogen stream above 300 °C. This catalytic behavior of the clusters is similar to that of the platinum group metals, which is attributable to the isoelectronicity of sulfur-coordinating molybdenum atom to the platinum group metals.

We also recommend Trading Suppliers and Manufacturers of PLATINUM(IV) SULFIDE (cas 12038-21-0). Pls Click Website Link as below: cas 12038-21-0 suppliers

Prev:Synthesis and utilization of platinum(II) dialkyldithiocarbamate precursors in aerosol assisted chemical vapor deposition of platinum thin films as counter electrodes for dye-sensitized solar cells
Next:Octahedral chalcogenide rhenium cluster complexes with imidazole)