A study of cis-dichlorobis(methylamine)platinum(II): Crystal and molecular structures of two crystal forms

Add time:07/28/2019    Source:sciencedirect.com

A new synthesis of cis-dichlorobis(methylamine)platinum(II) is described. It appears that during the crystallization process at least two types of crystals are formed. Form A is monoclinic with space group P2 1/n and unit cell dimensions a = 6.272, b = 15.726, c = 7.419Å, β = 99.86°, V = 721Å 3, Z = 4, R = 0.055. Form B is monoclinic, with space group P2 1/c and unit cell dimensions a = 16.078, b = 6.372, c = 21.459Å, β = 92.7°, V = 2196Å 3, Z = 12, R = 0.057. The two forms can be readily distinguished by IR spectroscopy.

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