Thermochemical study of tetravalent metal sulfate tetrahydrates: A4+(SO4)2(H2O)4 (A4+ = Zr, Ce, U)

Add time:07/27/2019    Source:sciencedirect.com

The syntheses, characterization, and calorimetric measurements of enthalpies of formation of four tetravalent metal sulfate tetrahydrates (A4+(SO4)2(H2O)4 (A4+ = Zr, Ce, U): α-Zr(SO4)2(H2O)4, α-Ce(SO4)2(H2O)4, β-Ce(SO4)2(H2O)4, and β-U(SO4)2(H2O)4) are reported. Direct calorimetric measurements showed that the formation enthalpies of these compounds from the corresponding oxides correlate with the eightfold coordination radius of the tetravalent cations. An energetic slope change is observed between the α- (Fddd) and β- (Pnma) forms and is consistent with previously reported studies.

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