A highly active bifunctional solid acid for di(1-naphthyl)methane hydroconversion

Add time:07/28/2019    Source:sciencedirect.com

Catalysts trifloromethanesulfonic acid (TFMSA)/treated attapulgite powder (TAP), Ni/TAP, and Ni-TFMSA/TAP with different Ni and TFMSA loadings were prepared. The typical catalysts were characterized with multiple instruments and used for catalyzing hydroconversion of di(1-naphthyl)methane (DNM), which was used as a coal-related model compound. The suitable loadings of Ni and TFMSA in Ni-TFMSA/TAP were determined to be 28.6% of Ni and 33% of TFMSA. Under optimal reaction conditions of 5 MPa of initial hydrogen pressure, 240 °C, and 4 h over Ni-TFMSA/TAP, DNM was completely converted, producing decalin and 1-methyldecalin as the main products. The result suggests that Ni-TFMSA/TAP is highly active for both cleaving the Car-Calk bond in DNM and hydrogenating the resulting naphthalene and 1-methylnaphthalene under mild conditions. Based on the identification of reaction products, the catalytic mechanism for DNM hydroconversion was discussed.

We also recommend Trading Suppliers and Manufacturers of 6-(1-NAPHTHYL)-6-OXOHEXANOIC ACID (cas 132104-09-7). Pls Click Website Link as below: cas 132104-09-7 suppliers

Prev:Reactions of dimesylthymidine with secondary amines: Easy access to 3′,5′-dideoxy-3′-substituted-5′-alkylaminothymidines - New classes of potential antiviral aminonucleosides.
Next:Reaction of 1-bromonaphthalene with PH3 in the t-BuOK/DMSO system: PCl3-free synthesis of di(1-naphthyl)phosphine and its oxide)