Comparison of structure-thermal property relationships for barium bis(1,1,1,5,5,5-hexafluoro-2,4-pentanedionate) polyether complexes

Add time:07/29/2019    Source:sciencedirect.com

The thermal properties of Ba(hfa)2, Ba(hfa)2(tetraglyme), Ba(hfa)2(18-crown-6), and Ba(hfa)2(diaza-18-crown-6) are investigated by comparing the results of thermogravimetric analysis (TGA) for these materials. All TGA measurements were made in helium at atmospheric pressure. Infrared, MS, NMR, and x-ray crystallographic measurements are compared for each of the complexes and correlations are made between the structure-specific information derived from these analyses and the thermal properties of the barium complexes.

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