Acetato-bridged acetoxy- and methoxy-palladium adducts of 1,5-cyclooctadiene

Add time:07/29/2019    Source:sciencedirect.com

The preparation of properties of two acetato-bridged binuclear acetoxy- and methoxypalladium(II) olefin adducts are described. The addition of the olefin double bond is found to be trans by an NMR spectral analysis. The oxypalladium adduct is found to exchange the oxy group rapidly indicating a facile equilibrium with what is presumed to be the dienepalladium(II) π-complex.

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