Reactions of hydridosilacyclobutanes with low-valent complexes of iron or platinum

Add time:07/31/2019    Source:sciencedirect.com

Unstable transition metal compounds formed from hydridosilacyclobutanes are described: 1-methyl-1-silacyclobutane reacts with nonacarbonyldiiron to give the complexes [Fe(CO)4(H){Si(Me)CH2CH2CH2}] and [Fe{CH2CH2CH2Si(H)Me}(CO)4], and with bis(triphenylphosphine)(ethylene)platinum(0) to give [Pt(H)(PPh3)2{Si(Me)CH2CH2CH2}].

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