Transition metal promoted higher-order cycloaddition reactions. [6+2] cycloaddition of a fischer carbene complex with tricarbonyl(cycloheptatriene) chromium(0)

Add time:07/29/2019    Source:sciencedirect.com

Photolytic reaction of pentacarbonyl [(methoxy)(methyl)carbene] chromium(0) with tricarbonyl(cycloheptatriene) chromium(0) afforded an isomeric mixture of bicyclo[4.2.1]nonanone products.

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