Determination of sulfate ion by potentiometric back-titration using sodium tetrakis (4-fluorophenyl) borate as a titrant and a titrant-sensitive electrode

Add time:07/17/2019    Source:sciencedirect.com

A potentiometric back-titration method for the determination of sulfate ions using a plasticized poly(vinyl chloride) membrane electrode sensitive to a titrant is described. The method is based on ion association between the excess of 2-aminoperimidinium added to the sulfate ion in the sample and sodium tetrakis (4-fluorophenyl) borate (FPB) in the titrant. The titration end-point was detected as a sharp potential change due to an increase in the concentration of the free FPB at the equivalence point. The end-point was detected even in the presence of a 20-fold excess of common cations and anions relative to the concentration of the sulfate ion within ∼2% of titration error. A linear relationship between the concentration of the sulfate ion and the end-point volume of the titrant exists in the sulfate ion concentration range from 2×10−4 to 3×10−3 mol l−1 using 10−2 mol l−1 FPB solutions as the titrant. The present method could be applied to determine sulfate ions in sea water.

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