Diversities of coordination architectures of metal Cd(II) 4-(N,N−bis(2-pyridyl)amino)methyl benzoic acid

Add time:07/31/2019    Source:sciencedirect.com

The coordination chemistry of the diatopic heteroscorpionate ligand 4-(N,N-bis-(2-pyridyl)-amino)methylbenzoic acid (HL) with CdX2 (X = Cl、Br、I)has been investigated for the construction of higher order metallosupramolecular architectures. Six new compounds were obtained by hydrothermal reactions with variations of the templating system. The structural diversities of these compounds demonstrated that the flexibility of the ligand plays important roles in the construction of such supra-molecular architectures.

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