Synthesis of a cumyl analogue in nitrothiazole series and SRN1 reaction at tertiary carbon

Add time:07/29/2019    Source:sciencedirect.com

A new alkylating agent, 2-(1-methyl-1-nitroethyl)-5-nitrothiazole, bearing a tertiary nitro nucleofuge, reacts with 2-nitropropane anion by SRN1 mechanism leading to the C-alkylation product.

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