Stereochemical course of the hydroboration of highly hindered steroidal olefins. A ready synthesis of 14β- and 8α, 14β-steroids

Add time:07/30/2019    Source:sciencedirect.com

Hydroboration of 5α-cholest-8-ene, 5α, 14β-cholest-8-ene and 5α, 14β-cholest-7-ene provides a simple route to oxygenated steroids with 14β- and 8α, 14β- unnatural stereochemistry.

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